STUDENT SPACE · TOPIC 1

Energy transfer and reaction pathways

Interpret and label energy changes and activation energy.

The essentials

  • An exothermic reaction transfers thermal energy to its surroundings. The surroundings become warmer.
  • An endothermic reaction takes thermal energy from the surroundings. The surroundings become cooler.
  • Eₐ is the minimum energy that colliding particles must have to react.

Key vocabulary

EnglishChinese
exothermic放热的
endothermic吸热的
enthalpy change焓变
activation energy活化能

Quick practice

Try each question before opening its hint or answer. Use paper for calculations and diagrams.

Question 1

An exothermic reaction has no activation energy. Explain why this is wrong.

Need a hint for Question 1?

Mark reactants, peak and products before subtracting energy levels.

Check Question 1

It may still require an initial energy input; negative ΔH does not mean Eₐ is zero.

Question 2

A mixture cools its surroundings. State the reaction type and the sign of ΔH.

Need a hint for Question 2?

If surroundings cool, where has their energy gone?

Check Question 2

Endothermic; ΔH is positive.

Question 3

Reactants: 20 kJ; peak: 90 kJ; products: 55 kJ. Draw and label the pathway, ΔH and Eₐ. Calculate both changes.

Need a hint for Question 3?

Subtract reactant energy from product energy and from peak energy separately.

Check Question 3

ΔH = +35 kJ; Eₐ = 70 kJ. Products are above reactants; Eₐ runs from reactants to the peak. Label energy and reaction progress.

Use Lesson 1 in your worksheet for written practice. Your teacher will discuss those answers in class.

PREDICT · TRY · EXPLAIN · 3–5 MINUTES

The bond energy account

Predict whether the reaction releases energy. Break the reactant bonds, then form the product bonds.

H₂ + Cl₂ → 2HCl

Average gas-phase bond energies in kJ mol⁻¹ of bonds. A simplified energy account per reaction as written; it does not show the reaction mechanism or activation energy.

Break: H–H = 436; Cl–Cl = 243. Form: 2 × H–Cl = 862.

Energy absorbed
Predict first
Energy released
Waiting for bond formation

Breaking bonds always requires energy; forming bonds releases energy. Explain the overall change using both parts of the account.

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