STUDENT SPACE · TOPIC 6

Carboxylic acids and esters

Explain acid reactions, ethanol oxidation and ester formation.

The essentials

  • 2CH₃COOH + Mg → (CH₃COO)₂Mg + H₂. CH₃COOH + NaOH → CH₃COONa + H₂O.
  • C₂H₅OH + 2[O] → CH₃COOH + H₂O. Acidified aqueous potassium manganate(VII) oxidises ethanol.
  • Carboxylic acid + alcohol ⇌ ester + water, using an acid catalyst.
  • The alcohol gives the alkyl name. The acid gives the name ending in -oate.

Key vocabulary

EnglishChinese
carboxylic acid羧酸
ester酯
oxidation氧化

Quick practice

Try each question before opening its hint or answer. Use paper for calculations and diagrams.

Question 1

Which two reactants form ethyl propanoate?

Need a hint for Question 1?

Split an ester at C(=O)–O. Identify the acid-derived and alcohol-derived portions.

Check Question 1

Ethanol and propanoic acid.

Question 2

Write the equation for ethanoic acid reacting with sodium carbonate.

Need a hint for Question 2?

A carbonate needs enough acid to form a salt, water and CO₂.

Check Question 2

2CH₃COOH + Na₂CO₃ → 2CH₃COONa + H₂O + CO₂.

Question 3

Name and draw the displayed ester from methanol and butanoic acid.

Need a hint for Question 3?

The alcohol supplies the alkyl part; the acid supplies the carboxylate part.

Check Question 3

Methyl butanoate: CH₃CH₂CH₂COOCH₃. Display C=O and every other bond.

Use Lesson 6 in your worksheet for written practice. Your teacher will discuss those answers in class.

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