STUDENT SPACE · TOPIC 3
Aluminium extraction
Explain cryolite, electrode reactions and replacement of carbon anodes.
The essentials
- Bauxite is the main ore. Purified aluminium oxide dissolves in molten cryolite.
- Al³⁺ + 3e⁻ → Al. Aluminium ions gain electrons at the negative cathode.
- Oxygen formed at the anode reacts with hot carbon: C + O₂ → CO₂.
Key vocabulary
| English | Chinese |
|---|
| bauxite | 铝土矿 |
| cryolite | 冰晶石 |
| anode | 阳极 |
Quick practice
Try each question before opening its hint or answer. Use paper for calculations and diagrams.
Question 1
Why is an aqueous solution unsuitable for producing aluminium at the cathode?
Need a hint for Question 1?
Identify the ion charge before adding electrons. Balance atoms and charge separately.
Check Question 1
Hydrogen forms in preference to aluminium in an aqueous electrolyte. A molten electrolyte is used.
Question 2
Give the purpose of cryolite.
Need a hint for Question 2?
Consider the melting point of pure aluminium oxide.
Check Question 2
Cryolite lowers the operating temperature and therefore the energy required.
Question 3
Write the oxide-ion half-equation and explain why the anode needs replacing.
Need a hint for Question 3?
Oxide ions lose electrons; the resulting gas reacts with carbon.
Check Question 3
2O²⁻ → O₂ + 4e⁻. Oxygen reacts with the carbon anode, consuming it.
Use Lesson 3 in your worksheet for written practice. Your teacher will discuss those answers in class.
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