STUDENT SPACE · TOPIC 3

Aluminium extraction

Explain cryolite, electrode reactions and replacement of carbon anodes.

The essentials

  • Bauxite is the main ore. Purified aluminium oxide dissolves in molten cryolite.
  • Al³⁺ + 3e⁻ → Al. Aluminium ions gain electrons at the negative cathode.
  • Oxygen formed at the anode reacts with hot carbon: C + O₂ → CO₂.

Key vocabulary

EnglishChinese
bauxite铝土矿
cryolite冰晶石
anode阳极

Quick practice

Try each question before opening its hint or answer. Use paper for calculations and diagrams.

Question 1

Why is an aqueous solution unsuitable for producing aluminium at the cathode?

Need a hint for Question 1?

Identify the ion charge before adding electrons. Balance atoms and charge separately.

Check Question 1

Hydrogen forms in preference to aluminium in an aqueous electrolyte. A molten electrolyte is used.

Question 2

Give the purpose of cryolite.

Need a hint for Question 2?

Consider the melting point of pure aluminium oxide.

Check Question 2

Cryolite lowers the operating temperature and therefore the energy required.

Question 3

Write the oxide-ion half-equation and explain why the anode needs replacing.

Need a hint for Question 3?

Oxide ions lose electrons; the resulting gas reacts with carbon.

Check Question 3

2O²⁻ → O₂ + 4e⁻. Oxygen reacts with the carbon anode, consuming it.

Use Lesson 3 in your worksheet for written practice. Your teacher will discuss those answers in class.

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